Official word from Adobe on Creative Cloud and Mavericks compatibility: Adobe and Apple have worked closely together to test Adobe Creative Cloud applications and Adobe Creative Suite 6 applications for reliability, performance and user experience when installed on Intel-based systems running Mac OS X Mavericks (v10.9).
All Adobe Creative Cloud and Creative Suite 6 products are compatible, but a few products require updates to the latest builds to work properly. Adobe Photoshop CS5, CS4 and CS3 were also tested with Mac OS X Mavericks and there are currently no major issues known.
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